The proof is based on the well known fact from Probabilty Theory that the expectation of the sum of random variables is the sum of their expectations, EVEN IF THEY ARE NOT INDEPENDENT. This is a deceptively powerful fact.
In math notation, if X and Y are random variables then
E(X+Y) = E(X) + E(Y)
in fact
E(aX+ bY) = aE(X) + bE(Y) where a,b are constants.
For example when running the Turn-River twice. X is the random variable based on the first two cards put out, Y is the random variable based on the second two cards. X and Y are 1 if they produce a win, 0 for a loss. Even though X and Y are not independent the above fact about expectations still holds.
When running it twice you're asking, what is
E(.5X + .5Y) ?
The additive Theorum for Expectatons says it's
.5E(X) + .5E(Y)
But if you ran either the first set of two cards or the second set of two cards by themselves, just one time using those cards, you should have no problem seeing that One Time, those two cards are just as likely to produce a win as any other two in the deck. In other words, One time by itself, E(X) is just the probabilty that X=1 as it should be. But the Y cards are just as good for running One Time by themselves ( just burn the other cards without looking )and E(Y) is the same probabilty of winning.
So,
.5E(X) + .5E(Y) =
.5*prob(the X cards produce a win when run one time) +
.5*prob(the Y cards produce a win when run one time) =
.5*prob(the X cards produce a win when run one time) +
.5*prob(the X cards produce a win when run one time) =
.5*(2*prob(the X cards produce a win when run one time)
= E(X) = Expectation running it once.
The nice thing about looking at it this way is that the same argument holds if you were running the whole board twice, or the whole board for an Omaha Hand where you would not want to list all the cases for cards that could come out.
It rests on two principles. The additivity for Expectations of Random Variables. And the observation that for the purposes of running it one time, with all cards sight unseen, any cards you want to pick out of the deck are as good as any others.